Beach | Riachuelos | ||||||||||
Sample | RIA1 | RIA2 | RIA3 | RIA4 | RIA5 | RIA6 | RIA7 | RIA8 | RIA9 | RIA10 | RIA11 |
La | 22.2 | 23.6 | 22.5 | 22.1 | 22.7 | 24.1 | 26.7 | 23.5 | 24.6 | 25.1 | 24.5 |
Ce | 46.2 | 47.3 | 45.6 | 44.6 | 45.1 | 48.2 | 46.2 | 47.9 | 46.5 | 45.5 | 46.6 |
Pr | 5.23 | 5.77 | 5.34 | 5.51 | 5.81 | 5.75 | 6.24 | 6.14 | 5.94 | 6.13 | 6.48 |
Nd | 20.3 | 22.8 | 20.9 | 21.6 | 23.1 | 22.8 | 24.0 | 22.8 | 21.6 | 24.6 | 26.7 |
Sm | 3.94 | 4.40 | 4.23 | 4.07 | 4.39 | 4.42 | 4.64 | 4.36 | 4.28 | 4.92 | 5.54 |
Eu | 1.35 | 1.44 | 1.25 | 1.27 | 1.26 | 1.49 | 1.81 | 1.38 | 1.28 | 1.57 | 1.63 |
Gd | 3.78 | 4.28 | 3.85 | 3.82 | 4.00 | 4.29 | 4.70 | 4.06 | 4.13 | 4.71 | 5.42 |
Tb | 0.52 | 0.58 | 0.51 | 0.51 | 0.53 | 0.58 | 0.64 | 0.59 | 0.52 | 0.62 | 0.75 |
Dy | 2.75 | 3.12 | 2.54 | 2.63 | 2.72 | 3.10 | 3.50 | 3.09 | 2.90 | 3.43 | 3.98 |
Ho | 0.53 | 0.58 | 0.49 | 0.49 | 0.52 | 0.59 | 0.69 | 0.53 | 0.57 | 0.63 | 0.75 |
Er | 1.51 | 1.66 | 1.38 | 1.35 | 1.41 | 1.67 | 2.02 | 1.47 | 1.51 | 1.79 | 2.12 |
Tm | 0.20 | 0.22 | 0.19 | 0.17 | 0.17 | 0.22 | 0.28 | 0.18 | 0.19 | 0.23 | 0.27 |
Yb | 1.33 | 1.38 | 1.21 | 1.13 | 1.09 | 1.43 | 1.90 | 1.18 | 1.19 | 1.55 | 1.80 |
Lu | 0.20 | 0.20 | 0.18 | 0.16 | 0.15 | 0.21 | 0.29 | 0.17 | 0.16 | 0.22 | 0.26 |
LREE | 98.0 | 104 | 98.0 | 98.0 | 101 | 105 | 108 | 105 | 103 | 106 | 110 |
HREE | 10.8 | 12.0 | 10.3 | 10.3 | 10.6 | 12.1 | 14.0 | 11.3 | 11.2 | 13.2 | 15.3 |
TREE | 110 | 117 | 110 | 109 | 113 | 119 | 124 | 117 | 115 | 121 | 127 |
Eu/Eu* | 1.05 | 1.00 | 0.93 | 0.97 | 0.90 | 1.03 | 1.17 | 0.99 | 0.92 | 0.99 | 0.90 |
Beach | Riachuelos | Palma Sola | |||||||||
Sample | RIA12 | RIA13 | RIA14 | RIA15 | Mean ± 1 s (n = 15) | PAL1 | PAL2 | PAL3 | PAL4 | PAL5 | PAL6 |
La | 25.6 | 25.9 | 31.8 | 26.1 | 24.70 ± 2.45 | 10.4 | 10.8 | 10.3 | 12.4 | 11.8 | 12.6 |
Ce | 44.6 | 51.5 | 62.6 | 45.7 | 47.60 ± 4.51 | 18.1 | 19.2 | 18.4 | 21.7 | 21.2 | 22.8 |
Pr | 5.24 | 6.39 | 8.41 | 5.34 | 5.98 ± 0.79 | 2.26 | 2.42 | 2.36 | 2.74 | 2.74 | 3.12 |
Nd | 22.4 | 25.5 | 33.4 | 22.8 | 23.7 ± 3.2 | 8.63 | 9.83 | 9.19 | 10.1 | 10.7 | 12.2 |
Sm | 4.42 | 4.98 | 6.51 | 4.18 | 4.62 ± 0.66 | 1.66 | 1.94 | 1.85 | 2.02 | 2.17 | 2.32 |
Eu | 1.37 | 1.54 | 1.93 | 1.37 | 1.46 ± 0.20 | 0.69 | 0.52 | 0.71 | 0.56 | 0.74 | 0.66 |
Gd | 3.74 | 4.92 | 6.23 | 4.21 | 4.41 ± 0.69 | 1.52 | 1.82 | 1.71 | 1.87 | 1.87 | 2.20 |
Tb | 0.55 | 0.67 | 0.8 | 0.61 | 0.60 ± 0.09 | 0.23 | 0.27 | 0.26 | 0.3 | 0.28 | 0.30 |
Dy | 3.02 | 3.54 | 4.23 | 2.96 | 3.17 ± 0.49 | 1.38 | 1.57 | 1.54 | 1.69 | 1.73 | 1.62 |
Ho | 0.58 | 0.68 | 0.79 | 0.57 | 0.60 ± 0.09 | 0.30 | 0.35 | 0.33 | 0.36 | 0.37 | 0.31 |
Er | 1.47 | 1.9 | 2.21 | 1.56 | 1.67 ± 0.28 | 0.82 | 0.92 | 0.91 | 1.02 | 1.02 | 0.91 |
Tm | 0.19 | 0.25 | 0.28 | 0.2 | 0.22 ± 0.04 | 0.11 | 0.11 | 0.12 | 0.12 | 0.13 | 0.13 |
Yb | 1.24 | 1.62 | 1.88 | 1.32 | 1.42 ± 0.27 | 0.86 | 0.97 | 0.95 | 0.93 | 1.17 | 0.84 |
Lu | 0.18 | 0.25 | 0.27 | 0.2 | 0.21 ± 0.04 | 0.13 | 0.15 | 0.15 | 0.14 | 0.18 | 0.12 |
LREE | 102 | 114 | 143 | 104 | 107.0 ± 10.9 | 41.0 | 44.2 | 42.1 | 49.0 | 48.6 | 53.1 |
HREE | 11.0 | 13.8 | 16.7 | 11.6 | 12.30 ± 1.93 | 5.36 | 6.17 | 5.96 | 6.44 | 6.76 | 6.43 |
TREE | 115 | 130 | 161 | 117 | 120.0 ± 12.8 | 47.1 | 50.9 | 48.7 | 56.0 | 56.1 | 60.2 |
Eu/Eu* | 1.00 | 0.94 | 0.91 | 0.99 | 0.98 ± 0.07 | 1.31 | 0.83 | 1.19 | 0.87 | 1.09 | 0.88 |
Beach | Palma Sola | ||||||||||
Sample | PAL7 | PAL8 | PAL9 | PAL10 | PAL11 | PAL13 | PAL15 | PAL17 | PAL20 | Mean ± 1 s (n = 15) | |
La | 9.90 | 10.9 | 11.6 | 13.8 | 13.7 | 9.85 | 13.2 | 11.6 | 10.8 | 11.60 ± 1.32 | |
Ce | 19.1 | 21.7 | 20.8 | 25.9 | 25.0 | 18.9 | 24.8 | 21.7 | 19.2 | 21.20 ± 2.51 | |
Pr | 2.55 | 2.68 | 2.54 | 3.44 | 3.36 | 2.38 | 3.35 | 2.94 | 2.50 | 2.76 ± 0.39 | |
Nd | 10.5 | 9.83 | 9.72 | 12.8 | 13.2 | 9.65 | 13.5 | 11.8 | 9.73 | 10.80 ± 1.55 | |
Sm | 2.34 | 1.84 | 1.95 | 2.46 | 2.78 | 2.04 | 2.95 | 2.52 | 1.95 | 2.19 ± 0.37 | |
Eu | 0.67 | 0.48 | 0.78 | 0.66 | 0.8 | 0.70 | 0.87 | 0.68 | 0.63 | 0.68 ± 0.10 | |
Gd | 2.07 | 1.71 | 1.78 | 2.32 | 2.38 | 1.94 | 2.79 | 2.16 | 1.69 | 1.99 ± 0.33 | |
Tb | 0.31 | 0.25 | 0.28 | 0.34 | 0.35 | 0.30 | 0.41 | 0.32 | 0.25 | 0.30 ± 0.05 | |
Dy | 1.85 | 1.42 | 1.65 | 1.98 | 2.06 | 1.80 | 2.42 | 1.86 | 1.56 | 1.74 ± 0.27 | |
Ho | 0.39 | 0.28 | 0.36 | 0.40 | 0.43 | 0.38 | 0.48 | 0.39 | 0.34 | 0.36 ± 0.05 | |
Er | 1.04 | 0.82 | 1.00 | 1.18 | 1.14 | 1.04 | 1.29 | 1.02 | 0.94 | 1.01 ± 0.13 | |
Tm | 0.13 | 0.12 | 0.11 | 0.12 | 0.13 | 0.14 | 0.13 | 0.12 | 0.11 | 0.12 ± 0.02 | |
Yb | 1.11 | 0.77 | 1.05 | 1.16 | 1.21 | 1.10 | 1.22 | 1.07 | 1.06 | 1.03 ± 0.14 | |
Lu | 0.17 | 0.11 | 0.16 | 0.17 | 0.18 | 0.17 | 0.18 | 0.16 | 0.17 | 0.16 ± 0.02 | |
LREE | 44.5 | 46.9 | 46.7 | 58.4 | 58.1 | 42.8 | 57.8 | 50.6 | 44.2 | 49.00 ± 5.93 | |
HREE | 7.07 | 5.48 | 6.38 | 7.73 | 7.89 | 6.86 | 8.92 | 7.10 | 6.12 | 6.71 ± 0.94 | |
TREE | 52.2 | 52.8 | 53.8 | 66.8 | 66.8 | 50.4 | 67.6 | 58.4 | 50.9 | 55.90 ± 6.74 | |
Eu/Eu* | 0.91 | 0.82 | 1.26 | 0.83 | 0.93 | 1.06 | 0.91 | 0.87 | 1.03 | 0.99 ± 0.16 |